Cooperative Sorption on Porous Materials

نویسندگان

چکیده

The functional shape of a sorption isotherm is determined by underlying molecular interactions. However, doubts have been raised on whether the mechanism can be understood in principle from analyzing curves via range competing models. We shown recently that it possible to translate interactions rigorous statistical thermodynamics. aim this paper fill gap between thermodynamic theory and experimental isotherms, especially microporous mesoporous materials. Based approach interfaces, we derived cooperative isotherm, as generalization Hill our solubilization model, without need for assumptions adsorption sites, layers, pore geometry. Instead, characterization sorbates, such sorbate-interface distribution function sorbate number distribution, well existence statistically independent units interface, underlies isotherm. Our applied directly literature data reveal few key system attributes control isotherm: sorbates free energy transferring saturated vapor interface. sorbate–sorbate interaction quantified also Kirkwood–Buff integral excess numbers.

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ژورنال

عنوان ژورنال: Langmuir

سال: 2021

ISSN: ['1520-5827', '0743-7463']

DOI: https://doi.org/10.1021/acs.langmuir.1c01236